From AP:

Then-Deputy Secretary of State Richard Armitage met with Washington Post reporter Bob Woodward in mid-June 2003, the same timeframe that the reporter has testified an administration official talked to him about CIA employee Valerie Plame. Armitage’s official State Department calendars, provided to The Associated Press under the Freedom of Information Act, show a one-hour meeting — marked “private appointment” — with Woodward on June 13, 2003.
UPDATE: Link here.